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- (Ed.)Brillouin scattering spectroscopy has been used to obtain an accurate (<1%) ρ-P equation of state (EOS) of 1:1 and 9:1 H2-He molar mixtures from 0.5 to 5.4 GPa at 296 K. Our calculated equations of state indicate close agreement with the experimental data right to the freezing pressure of hydrogen at 5.4 GPa. The measured velocities agree on average, within 0.5%, of an ideal mixing model. The ρ-P EOSs presented have a standard deviation of under 0.3% from the measured densities and under 1% deviation from ideal mixing. A detailed discussion of the accuracy, precision, and sources of error in the measurement and analyses of our equations of state is presented.more » « less
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Duwal, Sakun; Clay, Raymond C; Knudson, Marcus D; Boerner, Jeremiah; Cochrane, Kyle; Usher, Joshua; Dolan, Daniel; Farfan, Bernardo; de_La_Cruz, Chris; Banasek, Jacob; et al (, Physical Review B)
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Fei, Yingwei; Seagle, Christopher T.; Townsend, Joshua P.; McCoy, Chad A.; Boujibar, Asmaa; Driscoll, Peter; Shulenburger, Luke; Furnish, Michael D. (, Nature Communications)Abstract The essential data for interior and thermal evolution models of the Earth and super-Earths are the density and melting of mantle silicate under extreme conditions. Here, we report an unprecedently high melting temperature of MgSiO3at 500 GPa by direct shockwave loading of pre-synthesized dense MgSiO3(bridgmanite) using the Z Pulsed Power Facility. We also present the first high-precision density data of crystalline MgSiO3to 422 GPa and 7200 K and of silicate melt to 1254 GPa. The experimental density measurements support our density functional theory based molecular dynamics calculations, providing benchmarks for theoretical calculations under extreme conditions. The excellent agreement between experiment and theory provides a reliable reference density profile for super-Earth mantles. Furthermore, the observed upper bound of melting temperature, 9430 K at 500 GPa, provides a critical constraint on the accretion energy required to melt the mantle and the prospect of driving a dynamo in massive rocky planets.more » « less
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